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张祥标 副教授

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一、基本信息

张祥标(1980-),男,副教授。2007年毕业于吉林大学,获理学博士学位,曾在日本京都大学、香港科技大学和德国亚琛工业大学从事博士后研究。2013年10月进入安徽理工大学工作。

二、承担课程

物理化学、结构化学、工程化学和普通化学等理论及相关实验课程

三、研究方向

非线性光学、金属有机化学等理论研究

四、主要成果

(一)研究项目

安徽省自然科学基金等

(二)论文论著

1. Ming-Ran Du,# Xiang-Biao Zhang,* Sheng-Meng Si,# Feng Yang,# and Lei Wang,* Theoretical insights into C-C bond formation through isonitrile insertion into a Cp*Ti complex, RSC Adv., 2017, 7: 34816-34829.(# equal contribution)

2. Shuai Yang, Hui Tan, Wangqin Ji, Xiangbiao Zhang,* Pinhua Li, and Lei Wang,* Visible light-induced decarboxylative acylarylation of phenyl propiolates with α-oxocarboxylic acids to coumarins catalyzed by hypervalent iodine reagents under transition metal-free conditions, Adv. Synth. Catal., 2017, 359: 443-453.

3. Xiang-Biao Zhang,* Zhen-Yuan Hu, Gui-E Zhou, and Song Wang,* Theoretical insights into the synthesis of 2,3-dihydropyridines from unsaturated oximes by RhIII-catalyzed C-H activation – a DFT study, Eur. J. Org. Chem., 2017, 397-408.

4. Xiang-Biao Zhang,* Bin-Bin Yu, Sheng-Meng Si, and Song Wang, Theoretical prediction on the synthesis of 2,3-dihydropyridines through Co(III)-catalysed reaction of unsaturated oximes with alkenes, Int. J. Quantum Chem., 2017, 117(8): e25353.

5. Ji-Song Hu, Lei Zhang, Ling Qin, He-Gen Zheng*, and Xiang-Biao Zhang,* A rare three-coordinated zinc cluster-organic framework with two types of secondary building units, Chem. Commun., 2015, 51: 2899-2902.

6. Amanda G. Jarvis, Petr E. Sehnal, Somia E. Bajwa, Adrian C. Whitwood, Xiangbiao Zhang, Man Sing Cheung, Zhenyang Lin,* and Ian J. S. Fairlamb,* A remarkable cis- and trans-spanning dibenzylidene acetone diphosphine chelating ligand (dbaphos), Chem. Eur. J., 2013, 19: 6034-6043.

7. Xiang-Biao Zhang,* and Zhao Xi, A theoretical study of the mechanism for the homogeneous catalytic reversible dehydrogenation-hydrogenation of nitrogen heterocycles, Phys. Chem. Chem. Phys., 2011, 13: 3997-4004.

8. Xiang-Biao Zhang, Ji-Kang Feng,* and Ai-Min Ren, Theoretical study of one- and two-photon absorption properties of octupolar D2d and D3 bipyridyl metal complexes, J. Phys. Chem. A, 2007, 111: 1328-1338.

9. Xiang-Biao Zhang, Ji-Kang Feng,* and Ai-Min Ren, Theoretical study of the two-photon absorption properties of octupolar complexes with Cu(I), Zn(II) and Al(III) as centers and bis-cinnamaldimine as ligands, J. Organomet. Chem., 2007, 692: 3778-3787.

10. Xiang-Biao Zhang, Ji-Kang Feng,* Ai-Min Ren, and Chia-Chung Sun, Theoretical study of two-photon absorption properites for donor/acceptor-functionalized tetrakis(phenylethynyl)benzenes and bis(dehydrobenzoannuleno)benzenes, Opt. Mater., 2007, 29: 955-962.

11. Xiang-Biao Zhang, Ji-Kang Feng,* Ai-Min Ren, and Chia-Chung Sun, A comparative study of one- and two-photon absorption properties of meso-meso singly, meso-β doubly and meso-meso β-β β-β triply linked ZnII-porphyrin oligomers, J. Mol. Struc.-Theochem., 2007, 804: 21-89.

12. Xiang-Biao Zhang, Ji-Kang Feng,* Ai-Min Ren, and Chia-Chung Sun, Theoretical study of two-photon absorption properties of a series of ferrocene-based chromophores, J. Phys. Chem. A, 2006, 110: 12222-12230.

13. Xiang-Biao Zhang, Ji-Kang Feng,* Ai-Min Ren, and Chia-Chung Sun, Theoretical study of one- and two-photon absorption properties of olefin-linked paracyclophane oligomers, Can. J. Chem., 2006, 84: 1114-1123.

14. Xiang-Biao Zhang, Ji-Kang Feng,* Ai-Min Ren, and Xin Zhou, A comparative study of the two-photon absorption properties of new three-branched molecules – sumanene and triphenylene derivatives, Chem. Phys., 2006, 322: 269-278.

15. Xiang-Biao Zhang, Ji-Kang Feng,* Ai-Min Ren, Xin Zhou, and Chia-Chung Sun, A comparative study of the two-photon absorption properties of a new three-branched molecule – sumanene 3O derivative and relative molecules, Opt. Mater., 2006, 29: 199-205.

16. Xiang-Biao Zhang, Ji-Kang Feng,* Ai-Min Ren, Xiao-Jie Zhao, and Chia-Chung Sun, Theoretical study of two-photon absorption properties for triphenylamine(boron, aluminum)-cored dendritic compounds, J. Mol. Struc.-Theochem., 2006, 764: 69-75.

17. Xiang-Biao Zhang, Ji-Kang Feng,* Ai-Min Ren, and Chia-Chung Sun, A comparative study of two-photon properties of zinc(II)-porphyrin, meso-meso singly-linked zinc(II)-diporphyrin and zinc(II) meso, meso-coupled porphyrin dimer via hydrogen bonding interactions, J. Mol. Struc.-Theochem., 2006, 767: 165-173.

18. Xiang-Biao Zhang, Ji-Kang Feng,* Xin Zhou, and Ai-Min Ren, Theoretical investigation on a series of heterocycle-based compounds with large two-photon absorption cross-sections, J. Mol. Struc.-Theochem., 2005, 719: 207-212.

19. Xiang-Biao Zhang, Ji-Kang Feng,* Ai-Min Ren, and Chia-Chung Sun, Theoretical study of two-photon absorption properties of a series of tetra-paracyclophane derivatives, J. Mol. Struc.-Theochem., 2005, 756: 133-141.





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